Отправить статью по E-mail Synthesis and X-ray Crystallographic Study of [(UO2)2(C3H2O4)(Cl)2(C4H9NO)4]
- Авторы: Medvedkov Y.A.1, Grigor’ev M.S.2, Serezhkina L.B.1, Pushkin D.V.1, Serezhkin V.N.1
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Учреждения:
- Samara National Research University Named after Academician S.P. Korolev
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Выпуск: Том 63, № 3 (2018)
- Страницы: 338-342
- Раздел: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168506
- DOI: https://doi.org/10.1134/S0036023618030154
- ID: 168506
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Аннотация
Crystals of [(UO2)2(mal)(Cl)2(DMA)4] (mal2– is malonate ion and DMA is dimethylacetamide) have been synthesized and studied by X-ray crystallography. The key structure units are binuclear island complexes [(UO2)2(mal)(Cl)2(DMA)4], which belong to the A2Q02M61 crystal-chemical group (A = UO22+, Q02 = mal2–, M1 = Cl– and DMA) of uranyl complexes. The complexes form a framework through a system of intermolecular nonbonded interactions, which are characterized by means of the Voronoi–Direchlet molecular polyhedron method.
Об авторах
Ya. Medvedkov
Samara National Research University Named after Academician S.P. Korolev
Email: lserezh@samsu.ru
Россия, Samara, 443086
M. Grigor’ev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: lserezh@samsu.ru
Россия, Moscow, 119071
L. Serezhkina
Samara National Research University Named after Academician S.P. Korolev
Автор, ответственный за переписку.
Email: lserezh@samsu.ru
Россия, Samara, 443086
D. Pushkin
Samara National Research University Named after Academician S.P. Korolev
Email: lserezh@samsu.ru
Россия, Samara, 443086
V. Serezhkin
Samara National Research University Named after Academician S.P. Korolev
Email: lserezh@samsu.ru
Россия, Samara, 443086
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