Email this article Synthesis and X-ray Crystallographic Study of [(UO2)2(C3H2O4)(Cl)2(C4H9NO)4]
- Authors: Medvedkov Y.A.1, Grigor’ev M.S.2, Serezhkina L.B.1, Pushkin D.V.1, Serezhkin V.N.1
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Affiliations:
- Samara National Research University Named after Academician S.P. Korolev
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 63, No 3 (2018)
- Pages: 338-342
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168506
- DOI: https://doi.org/10.1134/S0036023618030154
- ID: 168506
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Abstract
Crystals of [(UO2)2(mal)(Cl)2(DMA)4] (mal2– is malonate ion and DMA is dimethylacetamide) have been synthesized and studied by X-ray crystallography. The key structure units are binuclear island complexes [(UO2)2(mal)(Cl)2(DMA)4], which belong to the A2Q02M61 crystal-chemical group (A = UO22+, Q02 = mal2–, M1 = Cl– and DMA) of uranyl complexes. The complexes form a framework through a system of intermolecular nonbonded interactions, which are characterized by means of the Voronoi–Direchlet molecular polyhedron method.
About the authors
Ya. A. Medvedkov
Samara National Research University Named after Academician S.P. Korolev
Email: lserezh@samsu.ru
Russian Federation, Samara, 443086
M. S. Grigor’ev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: lserezh@samsu.ru
Russian Federation, Moscow, 119071
L. B. Serezhkina
Samara National Research University Named after Academician S.P. Korolev
Author for correspondence.
Email: lserezh@samsu.ru
Russian Federation, Samara, 443086
D. V. Pushkin
Samara National Research University Named after Academician S.P. Korolev
Email: lserezh@samsu.ru
Russian Federation, Samara, 443086
V. N. Serezhkin
Samara National Research University Named after Academician S.P. Korolev
Email: lserezh@samsu.ru
Russian Federation, Samara, 443086
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