Cobalt(III) tetrabenzoporphyrin: Synthesis, spectral and coordination properties

G. M. Mamardashvili; N. V. Chizhova; E. Yu. Kaigorodova; N. Zh. Mamardashvili

doi:10.1134/S0036023617030123

Cobalt(III) tetrabenzoporphyrin: Synthesis, spectral and coordination properties

Autores: Mamardashvili G.M.¹, Chizhova N.V.¹, Kaigorodova E.Y.¹, Mamardashvili N.Z.¹
Afiliações:
1. Krestov Institute of Solution Chemistry
Edição: Volume 62, Nº 3 (2017)
Páginas: 301-308
Seção: Coordination Compounds
URL: https://bakhtiniada.ru/0036-0236/article/view/167439
DOI: https://doi.org/10.1134/S0036023617030123
ID: 167439

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Comparison of tetrabenzoporphyrin complexation reactions and transmetalation of cadmium(II) tetrabenzoporphyrinate with cobalt(II) acetate and chloride in dimethylformamide (DMF) has been carried out Cobalt(III) tetrabenzoporphyrinate has been prepared and identified. Acido ligands displacement in Co(III) tetrabenzoporphyrinate by pyridine, imidazole, and quinuclidine molecules has been studied.