Gel formation specifics in the synthesis of Mg(Fe 0.8 Ga 0.2 ) 2 O 4  by the glycine–nitrate method

M. N. Smirnova; L. V. Goeva; N. P. Simonenko; E. N. Beresnev; M. A. Kop’eva; V. A. Ketsko

doi:10.1134/S0036023616100193

Gel formation specifics in the synthesis of Mg(Fe_0.8Ga_0.2)₂O₄ by the glycine–nitrate method

Авторлар: Smirnova M.N.¹, Goeva L.V.¹, Simonenko N.P.¹, Beresnev E.N.¹, Kop’eva M.A.¹, Ketsko V.A.¹
Мекемелер:
1. Kurnakov Institute of General and Inorganic Chemistry
Шығарылым: Том 61, № 10 (2016)
Беттер: 1301-1306
Бөлім: Physical Methods of Investigation
URL: https://bakhtiniada.ru/0036-0236/article/view/166827
DOI: https://doi.org/10.1134/S0036023616100193
ID: 166827

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Аннотация

The gel formed in the synthesis of Mg(Fe_0.8Ga_0.2)₂O₄ powder from corresponding metal nitrates and glycine was studied by thermal and IR spectral analyses. Being a bidentate ligand, glycine was established to initiate the gel combustion reaction resulting in the oxide of the above composition. Based on the data on ΔH₂₉₈° and Cp of the reagents and reaction products, the thermodynamic parameters of this process were calculated.