Email this article A New Single-Molecule Magnet Based on a Cage Cobalt(II) Complex
- Authors: Aleshin D.Y.1,2, Pavlov A.A.1,3, Belova S.A.1, Efimov N.N.4, Belov A.S.1, Novikov V.V.1,3, Voloshin Y.Z.1,4
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Affiliations:
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Mendeleev University of Chemical Technology of Russia
- Moscow Institute of Physics and Technology
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 64, No 12 (2019)
- Pages: 1532-1537
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/169593
- DOI: https://doi.org/10.1134/S0036023619120027
- ID: 169593
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Abstract
A new cage cobalt(II) complex exhibiting a single-molecule magnet behavior has been synthesized by a template reaction on a metal ion as a matrix. The complex was characterized by elemental analysis and NMR spectroscopy. The magnetic properties have been studied by ac and dc magnetometry. The data obtained made it possible to determine the relaxation characteristics of this single-molecule magnet and compare them with those for a series of analogous recently reported cage cobalt(II) complexes.
About the authors
D. Yu. Aleshin
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Mendeleev University of Chemical Technology of Russia
Email: novikov84@ineos.ac.ru
Russian Federation, Moscow, 119991; Moscow, 125047
A. A. Pavlov
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Moscow Institute of Physics and Technology
Email: novikov84@ineos.ac.ru
Russian Federation, Moscow, 119991; Dolgoprudnyi, Moscow oblast, 141701
S. A. Belova
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: novikov84@ineos.ac.ru
Russian Federation, Moscow, 119991
N. N. Efimov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: novikov84@ineos.ac.ru
Russian Federation, Moscow, 119991
A. S. Belov
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: novikov84@ineos.ac.ru
Russian Federation, Moscow, 119991
V. V. Novikov
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Moscow Institute of Physics and Technology
Email: novikov84@ineos.ac.ru
Russian Federation, Moscow, 119991; Dolgoprudnyi, Moscow oblast, 141701
Ya. Z. Voloshin
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: novikov84@ineos.ac.ru
Russian Federation, Moscow, 119991; Moscow, 119991
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