Description of the Donor—Acceptor Bond in Terms of the Theory of Generalized Charges

详细

Previously, a universal relation for the energy and length of homopolar covalent bond has been derived with the use of the theory of generalized charges, which represents an asymptotic approximation for interatomic forces of the quantum-statistical model of a multicomponent electron gas. The article discusses the new implications of the theory, obtained to describe the donor-acceptor bond. The bond energy includes the contribution of the donor atom characteristic of a homopolar bond and the Coulomb interaction of the atoms, with allowance for the probability of fixation of the bond electrons on the acceptor. Regularities for the donor-acceptor bond length and energy have been discovered. In particular, for the particular case realized in hydrides, expressions are obtained for the length and bond energy versus the atomic number of the acceptor.