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Structural Features of Monomeric Octahedral Monooxo d2-Rhenium(V) Complexes [ReO(Ltrin)(Lmono)2] and [ReO(Ltrin)(Lbim)] with Oxygen Atoms of Tridentate Chelating (O, N, O) Ligands (Ltrin) (Review)


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Abstract

Structural features of 22 mononuclear octahedral monooxo d2-Re(V) complexes with tridentate chelating (О, N, О) ligands (Ltrin)—[ReO(Ltrin)(Lmono)2] and [ReO(Ltrin)(Lbim)] (Lmono is a monodentate ligand, is a bidentate ligand)—have been considered. Conditions for selecting ligands that can be located trans to the multiply bonded O(oxo) ligand are discussed.

About the authors

V. S. Sergienko

Kurnakov Institute of General and Inorganic Chemistry; All-Russia Institute of Scientific and Technical Information

Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 125190

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