Thermodynamic Properties of Monoclinic Samarium Orthotantalate  M -SmTaO 4

A. V. Tyurin; A. V. Khoroshilov; V. N. Gus’kov; G. E. Nikiforova; L. Kh. Baldaev; K. S. Gavrichev

doi:10.1134/S0036023618120215

Thermodynamic Properties of Monoclinic Samarium Orthotantalate M-SmTaO₄

作者: Tyurin A.V.¹, Khoroshilov A.V.¹, Gus’kov V.N.¹, Nikiforova G.E.¹, Baldaev L.K.², Gavrichev K.S.¹
隶属关系:
1. Kurnakov Institute of General and Inorganic Chemistry
2. Protection Coatings Technologic Systems
期: 卷 63, 编号 12 (2018)
页面: 1599-1604
栏目: Physical Methods of Investigation
URL: https://bakhtiniada.ru/0036-0236/article/view/169146
DOI: https://doi.org/10.1134/S0036023618120215
ID: 169146

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The isobaric heat capacity of samarium orthotantalate M-SmTaO₄ was measured by adiabatic and differential scanning calorimetry in the range 17–1115 K. Smoothed heat capacity values were used to calculate thermodynamic functions (entropy, enthalpy increment, and reduced Gibbs free energy) with the contribution from low-temperature (<17 K) magnetic transformations being ignored.