Email this article Theoretical Analysis of the Li, Ca, Ba∥F, WO4 System: Thermal Analysis of the Quaternary System LiF–BaF2–CaF2–BaWO4
- Authors: Akhmedova P.A.1, Gasanaliev A.M.2, Gamataeva B.Y.2, Khizrieva P.A.3
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Affiliations:
- Samsonov High School no. 667
- Institute of General and Inorganic Chemistry
- Dagestan State University of National Economy
- Issue: Vol 63, No 6 (2018)
- Pages: 837-842
- Section: Physicochemical Analysis of Inorganic Systems
- URL: https://bakhtiniada.ru/0036-0236/article/view/168792
- DOI: https://doi.org/10.1134/S0036023618060025
- ID: 168792
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Abstract
The differentiation of the quaternary reciprocal system Li, Ca, Ba∥F, WO4 was performed based on graph theory using special software. Stable and metastable secant complexes of the system were found using a matrix of reciprocal pairs of salts. For the first time, by a set of physicochemical analysis methods (differential thermal, visual polythermal, and X-ray powder diffraction analyses), based on the method of thermal analysis of successive projections of the composition polytope, the quaternary system LiF–BaF2–CaF2–BaWO4, which is a stable complex of the quaternary reciprocal system Li, Ca, Ba∥F, WO4, was studied and the coordinates of invariant points were determined.
About the authors
P. A. Akhmedova
Samsonov High School no. 667
Author for correspondence.
Email: amalaev00@mail.ru
Russian Federation, Moscow, 117403
A. M. Gasanaliev
Institute of General and Inorganic Chemistry
Email: amalaev00@mail.ru
Russian Federation, Makhachkala, 367003
B. Yu. Gamataeva
Institute of General and Inorganic Chemistry
Email: amalaev00@mail.ru
Russian Federation, Makhachkala, 367003
P. A. Khizrieva
Dagestan State University of National Economy
Email: amalaev00@mail.ru
Russian Federation, Makhachkala, 367008
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