Email this article Synthesis and Features of Crystal Structure of Scandium Hexa(isothiocyanato)chromate(III) Complex with Nicotinic Acid
- Authors: Cherkasova E.V.1, Pervukhina N.V.2, Kuratieva N.V.2,3, Cherkasova T.G.1
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Affiliations:
- Kuzbass State Technical University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 63, No 6 (2018)
- Pages: 776-780
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168758
- DOI: https://doi.org/10.1134/S0036023618060050
- ID: 168758
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Abstract
A double complex compound with a polymeric cation of composition [Sc2(C6H5NO2)3(C6H4NO2)3][Cr(NCS)6] has been synthesized by the reaction between Sc(NO3)3, K3[Cr(NCS)6], and nicotinic acid (C5H5NCOO) in an aqueous solution and studied by chemical analysis, IR spectroscopy, and X-ray diffraction. Crystals are hexagonal, space group P6322, Z = 2; a = 12.995(2) Å, c = 17.864(3) Å, V = 2612.3(7) Å3, ρcalc = 1.559 g/cm3.
About the authors
E. V. Cherkasova
Kuzbass State Technical University
Author for correspondence.
Email: ctg.htnv@kuzstu.ru
Russian Federation, Kemerovo, 650000
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: ctg.htnv@kuzstu.ru
Russian Federation, Novosibirsk, 630090
N. V. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
T. G. Cherkasova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, Kemerovo, 650000
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