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Structure of an Unordinary 1-D Cobalt(II) Polymer Formed upon the Dissolution of the Mononuclear Co(OOPh)2[O(H)Me]4 Adduct in Chloroform


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Abstract

The structure of the 1-D {[Co2(μ,η2-OOCPh)(μ-OOCPh)2(O(H)Me)2](μ-OOCPh)(HCCl3)}n polymer formed upon the dissolution of single crystals of the mononuclear Co(OOPh)2[O(H)Me]4 adduct containing coordinated labile methanol molecules in boiling chloroform was studied by X-ray diffraction.

About the authors

A. A. Grineva

Kurnakov Institute of General and Inorganic Chemistry

Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991

R. R. Datchuk

Kurnakov Institute of General and Inorganic Chemistry

Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991

M. A. Uvarova

Kurnakov Institute of General and Inorganic Chemistry

Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991

L. I. Demina

Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071

S. E. Nefedov

Kurnakov Institute of General and Inorganic Chemistry

Author for correspondence.
Email: snef@igic.ras.ru
Russian Federation, Moscow, 119991

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