Email this article Structural Features of [{MoO2(Lbi)}2(μ-O)] Based Oxomolybdenum(VI) Complexes with Five-Coordinate Molybdenum(VI)
- Authors: Sergienko V.S.1,2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- All-Russia Institute of Scientific and Technical Information
- Issue: Vol 63, No 4 (2018)
- Pages: 460-467
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168589
- DOI: https://doi.org/10.1134/S0036023618040174
- ID: 168589
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Abstract
Structural features of eight binuclear complexes with the general formula [{MoO2(Lbin)}2(μ-O)] (I–VIII) (Lbi is a bidentate chelate ligand, n = 1–8), in which the coordination number of Mo atoms is five, are considered. The parameter τ = (A–B)/60, where A and B are the greatest bond angles among the ten bond angles at the Mo atoms in coordination pentahedra, can be used as a criterion characterizing the coordination polyhedron of the molybdenum atom in complexes I–VIII. The parameter τ is zero for an ideal square pyramid and unity for an ideal trigonal bipyramid.
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry; All-Russia Institute of Scientific and Technical Information
Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 125315
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