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Study of the Structure of Lithium Thiocyanate Complexes with Benzo-15-Crown-5 by X-ray Diffraction and IR Spectroscopy


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Abstract

The complex formation of lithium thiocyanate with benzo-15-crown-5 (B15C5) was studied. The possibility of formation of both anhydrous and crystal water-containing complexes was demonstrated. The complexes LiB15C5NCS and LiB15C5H2ONCS were synthesized and characterized by X-ray diffraction and IR spectroscopy.

About the authors

L. G. Kuz’mina

Kurnakov Institute of General and Inorganic Chemistry

Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991

L. I. Demina

Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071

S. V. Demin

Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071

N. A. Shokurova

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119071

V. I. Zhilov

Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry

Author for correspondence.
Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071

A. Yu. Tsivadze

Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry

Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071

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