Study of the Structure of Lithium Thiocyanate Complexes with Benzo-15-Crown-5 by X-ray Diffraction and IR Spectroscopy
- Authors: Kuz’mina L.G.1, Demina L.I.1,2, Demin S.V.1,2, Shokurova N.A.2, Zhilov V.I.1,2, Tsivadze A.Y.1,2
-
Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Issue: Vol 63, No 3 (2018)
- Pages: 357-360
- Section: Physical Methods of Investigation
- URL: https://bakhtiniada.ru/0036-0236/article/view/168518
- DOI: https://doi.org/10.1134/S0036023618030129
- ID: 168518
Cite item
Abstract
The complex formation of lithium thiocyanate with benzo-15-crown-5 (B15C5) was studied. The possibility of formation of both anhydrous and crystal water-containing complexes was demonstrated. The complexes LiB15C5NCS and LiB15C5H2ONCS were synthesized and characterized by X-ray diffraction and IR spectroscopy.
About the authors
L. G. Kuz’mina
Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991
L. I. Demina
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071
S. V. Demin
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071
N. A. Shokurova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119071
V. I. Zhilov
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071
A. Yu. Tsivadze
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119071
Supplementary files
