Email this article Synthesis and Crystal Structure of Dinitratotetra(hexamethylphosphoric Triamide)-Lanthanum(III)Tetra(Isothiocyanato)Diammine Chromate(III)
- Authors: Bobrovnikova A.A.1, Peresypkina E.V.2,3, Virovets A.V.2,3, Cherkasova T.G.1, Tatarinova E.S.1
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Affiliations:
- Kuzbass State Technical University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 63, No 1 (2018)
- Pages: 34-39
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168316
- DOI: https://doi.org/10.1134/S0036023618010047
- ID: 168316
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Abstract
A new coordination compound having the formula [La(HMPA)4(NO3)2][Cr(NH3)2(NCS)4] (I), where HMPA is ((CH3)2N)3PO, has been synthesized and studied by X-ray diffraction. Studied crystals of compound I are monoclinic, space group P21/n, a = 15.0360(3) Å, b = 15.1214(3) Å, c = 26.7529(7) Å, β = 100.6610(10)°, V = 5977.7(9) Å3, Z = 2, ρcalc = 1.442 g/cm3, and R1 = 0.0453 for 7344 reflections with Fo ≥ 4σ(Fo).
About the authors
A. A. Bobrovnikova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, Kemerovo, 650000
E. V. Peresypkina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
A. V. Virovets
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
T. G. Cherkasova
Kuzbass State Technical University
Author for correspondence.
Email: ctg.htnv@kuzstu.ru
Russian Federation, Kemerovo, 650000
E. S. Tatarinova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, Kemerovo, 650000
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