Email this article Dioxomolybdenum(VI) Complexes with R1-Substituted Salicylidene Allylimines (Hln): Synthesis and Structure. Crystal Structure of [MoO2(L1)2] (R1 = H)
- Authors: Sergienko V.S.1,2, Abramenko V.L.3, Gorbunova Y.E.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- All-Russia Institute of Scientific and Technical Information
- Dal’ East Ukrainian National University
- Issue: Vol 63, No 1 (2018)
- Pages: 28-33
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/168312
- DOI: https://doi.org/10.1134/S003602361801014X
- ID: 168312
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Abstract
The synthesis and X-ray diffraction analysis of [MoO2(L1)2] has been performed. The molybdenum atom has a cis(Ooxo), cis(NL), trans(OL) octahedral coordination. The average bond lengths (Å): Mo–O(oxo), 1.691; Mo–N(L1), 2.351; Mo–O(L1), 1.954.
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry; All-Russia Institute of Scientific and Technical Information
Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 125190
V. L. Abramenko
Dal’ East Ukrainian National University
Email: sergienko@igic.ras.ru
Ukraine, Lugansk, 91034
Yu. E. Gorbunova
Kurnakov Institute of General and Inorganic Chemistry
Email: sergienko@igic.ras.ru
Russian Federation, Moscow, 119991
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