Email this article Crystal structure of two polymorphs of molybdenyl salicylidene-2-furfuriliminate (HL1) [MoO2(L1)2]
- Authors: Sergienko V.S.1,2, Abramenko V.L.3, Gorbunova Y.E.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- All-Russia Institute of Scientific and Technical Information
- Dal East Ukrainian National University
- Issue: Vol 62, No 7 (2017)
- Pages: 900-904
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/167819
- DOI: https://doi.org/10.1134/S0036023617070208
- ID: 167819
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Abstract
The crystal structures of two polymorphs of molybdenyl salicylidene-2-furfuryliminate [MoO2(L1)2] have been solved by X-ray diffraction. Both complexes crystallize in centrosymmetric and non-centrosymmetric space groups (P21/c and Р21, respectively) of monoclinic system and have similar structures and close geometric parameters. The Мо atoms have a distorted octahedral coordination to two terminal oxo ligands in cis-positions to each other and two pairs of the oxygen atoms (cis- to О(oxo)) and the nitrogen atoms (trans- to О(oxo)) of two bidentate chelate ligands (L1)–.
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry; All-Russia Institute of Scientific and Technical Information
Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; ul. Usievicha 20, Moscow, 125190
V. L. Abramenko
Dal East Ukrainian National University
Email: sergienko@igic.ras.ru
Ukraine, Molodezhnyi kvartal 20a, Lugansk, 91034
Yu. E. Gorbunova
Kurnakov Institute of General and Inorganic Chemistry
Email: sergienko@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
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