Email this article New double complex salt [PdEn2]3[Rh(NO2)6]2 · 2.67H2O: Synthesis, crystal structure, and thermal properties
- Authors: Kirilovich A.K.1, Plyusnin P.E.1,2, Piryazev D.A.1,2, Gromilov S.A.1,2, Korenev S.V.1,2
-
Affiliations:
- Novosibirsk State University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 62, No 7 (2017)
- Pages: 886-892
- Section: Synthesis and Properties of Inorganic Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/167812
- DOI: https://doi.org/10.1134/S0036023617070099
- ID: 167812
Cite item
Open Access
Access granted
Subscription Access
Abstract
The crystal structure of the double complex salt (DCS) [PdEn2]3[Rh(NO2)6]2 • 2.67H2O (I) has been determined by X-ray diffraction. Crystals are triclinic, space group \(P\bar 1\), Z = 4, a = 9.2331(3) Å, b = 9.9136(4) Å, c = 13.7824(5) Å, α = 84.3230(14)°, β = 89.9655(14)°, γ = 66.7272(13)°, V = 1152.19(7) Å3, ρcalcd = 2.141 g/cm3, R = 0.0279. The thermal behavior of complex salt I has been studied in various gas atmospheres. The end product of thermolysis in reductive atmosphere is a mixture of Pd0.45Rh0.55 and Pd0.95Rh0.05 solid solutions. The end product of thermolysis in an inert atmosphere is a homogeneous Pd0.6Rh0.4 solid solution.
About the authors
A. K. Kirilovich
Novosibirsk State University
Email: plus@niic.nsc.ru
Russian Federation, ul. Pirogova 2, Novosibirsk, 630090
P. E. Plyusnin
Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: plus@niic.nsc.ru
Russian Federation, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
D. A. Piryazev
Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: plus@niic.nsc.ru
Russian Federation, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
S. A. Gromilov
Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: plus@niic.nsc.ru
Russian Federation, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
S. V. Korenev
Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: plus@niic.nsc.ru
Russian Federation, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
Supplementary files
