Email this article Hexafluorosilicates of cobalt(II) complexes with dimethylsulfoxide and dimethylformamide
- Authors: Cherkasova T.G.1, Bagryanskaya I.Y.2,3, Pervukhina N.V.4, Kurat’eva N.V.4,3, Medvedev V.V.1, Tatarinova E.S.1, Cherkasova E.V.1
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Affiliations:
- Kuzbass State Technical University
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 62, No 6 (2017)
- Pages: 760-765
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/167742
- DOI: https://doi.org/10.1134/S003602361706002X
- ID: 167742
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Abstract
New double complexes [Co(DMSO)6][SiF6] ⋅ 2H2O (I) and [Co(DMF)3(H2O)3][SiF6] ⋅ DMF (II) have been synthesized and studied by IR spectroscopy and X-ray diffraction. Crystals of complex I belong to the tetragonal symmetry system, space group R3̄, Z = 3, a = 11.8232(3) Å, c = 18.4699(5) Å, V = 2235.97(10) Å3, ρcalc = 1.573 g/cm3. Crystals of complex II are triclinic, space group P1̄, Z = 2, a = 8.6264(4) Å, b = 10.1419(4) Å, c = 13.9657(6) Å, α = 100.847(2)°, β = 98.549(2)°, γ = 93.479(2)°, V = 1181.71(9) Å3, ρcalc = 1.539 g/cm3.
About the authors
T. G. Cherkasova
Kuzbass State Technical University
Author for correspondence.
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
I. Yu. Bagryanskaya
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
N. V. Kurat’eva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
V. V. Medvedev
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
E. S. Tatarinova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
E. V. Cherkasova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
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