Email this article Structural features of monomeric octahedral d2-rhenium(V) monooxo complexes with the oxygen atoms of bidentate chelate (О,S and О,С) acido ligands
- Authors: Sergienko V.S.1,2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry
- All-Russia Institute of Scientific and Technical Information
- Issue: Vol 62, No 6 (2017)
- Pages: 751-759
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/167737
- DOI: https://doi.org/10.1134/S0036023617060195
- ID: 167737
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Abstract
Some structural features of 12 mononuclear octahedral d2-Re(V) monooxo complexes (I–ХII) with the oxygen atoms of bidentate chelate (О,S) acido ligands (Lig) and a similar complex with the oxygen atom of a bidentate chelate (О,С) monoanionic ligand (XIII) have been considered. The O(Lig) atoms are in trans positions to О(oxo) ligands in eleven complexes I–Х and XIII and in cis positions to oxo ligands in two complexes XI and XII. In all the cases, Re–Otrans bonds are longer than Re–Ocis (or Re–Ostand).
About the authors
V. S. Sergienko
Kurnakov Institute of General and Inorganic Chemistry; All-Russia Institute of Scientific and Technical Information
Author for correspondence.
Email: sergienko@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; ul. Usievicha 20, Moscow, 125190
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