Email this article Association of bromate ion in nonaqueous solutions of alkali metal salts
- Authors: Mikhailov G.P.1, Rabchuk L.V.1, Lazarev V.V.1
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Affiliations:
- Ufa State Aviation Technical University
- Issue: Vol 62, No 4 (2017)
- Pages: 523-526
- Section: Physical Chemistry of Solutions
- URL: https://bakhtiniada.ru/0036-0236/article/view/167577
- DOI: https://doi.org/10.1134/S003602361704012X
- ID: 167577
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Abstract
Manifestations of ion association of lithium cation with BrO3- ion in the vibrational spectrum have been studied by IR spectroscopy. The microstructure of the bromate ion with lithium cation in a contact ion pair in an aprotic solvent has been determined by the density functional theory method in the B3LYP/cc-pVTZ approximation, and the vibrational spectrum of coordinated bromate ion has been calculated.
About the authors
G. P. Mikhailov
Ufa State Aviation Technical University
Author for correspondence.
Email: gpmihailov@mail.ru
Russian Federation, Ufa, Bashkortostan, 450000
L. V. Rabchuk
Ufa State Aviation Technical University
Email: gpmihailov@mail.ru
Russian Federation, Ufa, Bashkortostan, 450000
V. V. Lazarev
Ufa State Aviation Technical University
Email: gpmihailov@mail.ru
Russian Federation, Ufa, Bashkortostan, 450000
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