Email this article Magnesium(II) and cadmium(II) octaphenyltetraazaporphyrinates in metal exchange reaction with MnCl2 in DMSO
- Authors: Zvezdina S.V.1, Chizhova N.V.1, Mamardashvili N.Z.1
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Affiliations:
- Krestov Institute of Solution Chemistry
- Issue: Vol 62, No 4 (2017)
- Pages: 517-522
- Section: Physical Chemistry of Solutions
- URL: https://bakhtiniada.ru/0036-0236/article/view/167573
- DOI: https://doi.org/10.1134/S0036023617040222
- ID: 167573
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Abstract
Reaction kinetics of metal exchange of Mg(II) and Cd(II) octaphenyltetraazaporphynates with MnCl2 in DMSO has been studied by spectrophotometry. Kinetic parameters of the metal exchange reaction have been determined. Possible stoichiometric reaction mechanism has been suggested. Effect of solvent and salt solvate nature on the rate of metal exchange reaction has been revealed.
About the authors
S. V. Zvezdina
Krestov Institute of Solution Chemistry
Author for correspondence.
Email: svvr@isc-ras.ru
Russian Federation, Ivanovo, 153045
N. V. Chizhova
Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
Russian Federation, Ivanovo, 153045
N. Zh. Mamardashvili
Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
Russian Federation, Ivanovo, 153045
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