Email this article Products of complexation in the Cu(CH3CОО)2–2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide–salicylaldehyde–isopropanol system
- Authors: Pulya A.V.1, Seifullina I.I.1, Skorokhod L.S.1, Efimov N.N.2, Ugolkova E.A.2, Vlasenko V.G.3, Levchenkov S.I.4, Trigub A.L.5, Zubavichus Y.V.5, Minin V.V.2
-
Affiliations:
- Mechnikov Odessa National University
- Kurnakov Institute of General and Inorganic Chemistry
- Research Institute of Physics
- Southern Research Center of the Russian Academy of Sciences
- Russian Research Center “Kurchatov Institute”
- Issue: Vol 62, No 2 (2017)
- Pages: 191-196
- Section: Physical Methods of Investigation
- URL: https://bakhtiniada.ru/0036-0236/article/view/167379
- DOI: https://doi.org/10.1134/S0036023617020139
- ID: 167379
Cite item
Open Access
Access granted
Subscription Access
Abstract
Copper(II) complexes isolated from the Cu(CH3COO)2–2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide (Hydr)–salicylaldehyde (HSal)–isopropanol system [Cu2(HydrSal)2(μ-CH3COO)] (I), [Cu(HydrSal)2] (II) (HydrSal (hydrazone)is the condensation product of hydrazide and salicylaldehide) are synthesized and investigated. The complexes are characterized by elemental analysis, electrical conductivity measurements, and IR spectroscopy. The composition and structure of the Cu2+ coordination core are determined by ESR spectroscopy (I), magnetic susceptibility measurements and extended X-ray absorption fine structure (EXAFS) spectroscopy (II).
About the authors
A. V. Pulya
Mechnikov Odessa National University
Author for correspondence.
Email: angelinarud@rambler.ru
Ukraine, Odessa, 65082
I. I. Seifullina
Mechnikov Odessa National University
Email: angelinarud@rambler.ru
Ukraine, Odessa, 65082
L. S. Skorokhod
Mechnikov Odessa National University
Email: angelinarud@rambler.ru
Ukraine, Odessa, 65082
N. N. Efimov
Kurnakov Institute of General and Inorganic Chemistry
Email: angelinarud@rambler.ru
Russian Federation, Moscow, 119991
E. A. Ugolkova
Kurnakov Institute of General and Inorganic Chemistry
Email: angelinarud@rambler.ru
Russian Federation, Moscow, 119991
V. G. Vlasenko
Research Institute of Physics
Email: angelinarud@rambler.ru
Russian Federation, Rostov-on-Don, 344006
S. I. Levchenkov
Southern Research Center of the Russian Academy of Sciences
Email: angelinarud@rambler.ru
Russian Federation, Rostov-on-Don
A. L. Trigub
Russian Research Center “Kurchatov Institute”
Email: angelinarud@rambler.ru
Russian Federation, Moscow, 123182
Ya. V. Zubavichus
Russian Research Center “Kurchatov Institute”
Email: angelinarud@rambler.ru
Russian Federation, Moscow, 123182
V. V. Minin
Kurnakov Institute of General and Inorganic Chemistry
Email: angelinarud@rambler.ru
Russian Federation, Moscow, 119991
Supplementary files
