Email this article Double complex [Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4: Synthesis and crystal structure
- Authors: Cherkasova T.G.1, Bagryanskaya I.Y.2,3, Pervukhina N.V.4, Vornakov A.L.1, Cherkasova E.V.1, Kuratieva N.V.3,4
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Affiliations:
- Kuzbass State Technical University
- Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 62, No 2 (2017)
- Pages: 182-186
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/167372
- DOI: https://doi.org/10.1134/S003602361702005X
- ID: 167372
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Abstract
[Mn2(C11H13N3O)6(H2O)2][Cr(NH3)2(NCS)4]4 (I) has been synthesized by the reaction between MnCl2 · H2O, NH4[Cr(NH3)2(NCS)4] · 0.5H2O and 4-aminoantipyrine (C11H13N3O) in an aqueous solution, and its structure has been determined by IR spectroscopy and X-ray diffraction. Crystals of complex I are triclinic, space group \(P\bar 1\), Z = 1, a = 13.2378(5) Å, b = 15.7796(5) Å, c = 16.7703(6) Å, α = 83.194(2)°, β = 75.874(2)°, γ = 66.529(1)°, V = 3115.2(2) Å3, and ρcalcd = 1.407 g/cm3.
About the authors
T. G. Cherkasova
Kuzbass State Technical University
Author for correspondence.
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
I. Yu. Bagryanskaya
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 9, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: ctg.htnv@kuzstu.ru
Russian Federation, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
A. L. Vornakov
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
E. V. Cherkasova
Kuzbass State Technical University
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Vesennyaya 28, Kemerovo, 650000
N. V. Kuratieva
Novosibirsk National Research State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: ctg.htnv@kuzstu.ru
Russian Federation, ul. Pirogova 2, Novosibirsk, 630090; pr. Akademika Lavrent’eva 3, Novosibirsk, 630090
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