Email this article Some novel organometallic MnIII complexes with porphine and 1,6-diaminohexane
- Authors: Bharati S.L.1, Chaurasia P.K.1, Yadava S.1
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Affiliations:
- Department of Chemistry
- Issue: Vol 61, No 2 (2016)
- Pages: 232-238
- Section: Physical Methods of Investigation
- URL: https://bakhtiniada.ru/0036-0236/article/view/167149
- DOI: https://doi.org/10.1134/S0036023616020212
- ID: 167149
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Abstract
A novel series of MnIII complexes with 5,10,15,20-tetra(p-tolylporphine) and 1,6-diaminohexane has been synthesized. These complexes have been characterized by UV/Vis, IR, ESI-mass spectra, elemental analysis, conductivity and magnetic susceptibility measurements. These MnIII porphyrins exhibited a blue shift in soret band in comparison to non-metallated porphyrins. The molar conductance values of these complexes show their non-electrolytic nature in ethanol. The tentative structures have also been proposed. All the complexes have good level of water solubility due to which they may have medicinal as well as other valuable biological applications.
About the authors
Shashi Lata Bharati
Department of Chemistry
Author for correspondence.
Email: shashilatachem@gmail.com
India, Nirjuli, Arunachal Pradesh
Pankaj Kumar Chaurasia
Department of Chemistry
Email: shashilatachem@gmail.com
India, Gorakhpur, 273009, U.P.
Sudha Yadava
Department of Chemistry
Email: shashilatachem@gmail.com
India, Gorakhpur, 273009, U.P.
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