Email this article Tetraphenylantimony N-benzoylglycinate: synthesis and structure
- Authors: Sharutin V.V.1, Sharutina O.K.1, Khnykina K.A.1
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Affiliations:
- South Ural State University (National Research University)
- Issue: Vol 61, No 2 (2016)
- Pages: 180-182
- Section: Coordination Compounds
- URL: https://bakhtiniada.ru/0036-0236/article/view/167127
- DOI: https://doi.org/10.1134/S0036023616020194
- ID: 167127
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Abstract
Tetraphenylantimony N-benzoylglycinate (I) has been synthesized by the reaction between pentaphenylantimony and N-benzoylglycine in toluene. According to X-ray diffraction data, the antimony atom in a molecule of complex I has a trigonal bipyramidal coordination to the oxygen atom in axial position. The Sb‒Ceq, Sb‒Cax, and Sb‒O bond lengths are 2.116(6)‒2.138(6), 2.183(6), and 2.200(4) Å, respectively. The intramolecular Sb⋯O=C distance between the carbonyl oxygen atom and the central antimony atom is 3.35(2) Å.
About the authors
V. V. Sharutin
South Ural State University (National Research University)
Author for correspondence.
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
O. K. Sharutina
South Ural State University (National Research University)
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
K. A. Khnykina
South Ural State University (National Research University)
Email: vvsharutin@rambler.ru
Russian Federation, pr. Lenina 76, Chelyabinsk, 454080
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