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Synthesis and study of the heat capacity of orthovanadate TbVO4 in the range 5–859 K


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Resumo

The heat capacity of TbVO4 has been measured by the adiabatic calorimetry (5–346 K) and differential scanning calorimetry (344–859 K) methods. The Cp = f(T) plot has an extreme point (32 K). The thermodynamic properties of the oxide compounds have been calculated from the experimental data. A general equation that describes the heat capacity of terbium orthovanadate as a function of temperature in the range 35–859 K has been derived.

Sobre autores

L. Denisova

Institute of Non-Ferrous Metals and Materials Science

Email: antluba@mail.ru
Rússia, ul. Krasnoyarskii Rabochii 95, Krasnoyarsk, 660025

Yu. Kargin

Baikov Institute of Metallurgy and Materials Science

Email: antluba@mail.ru
Rússia, Leninskii pr. 49, Moscow, 119991

L. Chumilina

Institute of Non-Ferrous Metals and Materials Science

Email: antluba@mail.ru
Rússia, ul. Krasnoyarskii Rabochii 95, Krasnoyarsk, 660025

V. Denisov

Institute of Non-Ferrous Metals and Materials Science

Email: antluba@mail.ru
Rússia, ul. Krasnoyarskii Rabochii 95, Krasnoyarsk, 660025

K. Gavrichev

Kurnakov Institute of General and Inorganic Chemistry

Email: antluba@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991

M. Ryumin

Kurnakov Institute of General and Inorganic Chemistry

Email: antluba@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991

A. Tyurin

Kurnakov Institute of General and Inorganic Chemistry

Autor responsável pela correspondência
Email: antluba@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991

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