Conformation of diethylglyoxime in uranyl complexes


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New complexes of uranyl with diethylglyoxime have been synthesized and studied. A feature of these complexes is the tetradentate bridging coordination of the ligand in both cis- and trans-conformations. The structure of organic ligand C6H12N2O2 and binuclear complex (CN3H6)4[(UO2)2(C6H10N2O2)(CO3)(C2O4)2] ∙ H2O have been determined by X-ray diffraction.

Sobre autores

A. Beirakhov

Kurnakov Institute of General and Inorganic Chemistry

Autor responsável pela correspondência
Email: abey@igic.ras.ru
Rússia, Leninskii pr. 31, Moscow, 119991

I. Orlova

Kurnakov Institute of General and Inorganic Chemistry

Email: abey@igic.ras.ru
Rússia, Leninskii pr. 31, Moscow, 119991

A. Rotov

Kurnakov Institute of General and Inorganic Chemistry

Email: abey@igic.ras.ru
Rússia, Leninskii pr. 31, Moscow, 119991

E. Il’in

Kurnakov Institute of General and Inorganic Chemistry

Email: abey@igic.ras.ru
Rússia, Leninskii pr. 31, Moscow, 119991

L. Goeva

Kurnakov Institute of General and Inorganic Chemistry

Email: abey@igic.ras.ru
Rússia, Leninskii pr. 31, Moscow, 119991

M. Surazhskaya

Kurnakov Institute of General and Inorganic Chemistry

Email: abey@igic.ras.ru
Rússia, Leninskii pr. 31, Moscow, 119991

A. Churakov

Kurnakov Institute of General and Inorganic Chemistry

Email: abey@igic.ras.ru
Rússia, Leninskii pr. 31, Moscow, 119991

Yu. Mikhailov

Kurnakov Institute of General and Inorganic Chemistry

Email: abey@igic.ras.ru
Rússia, Leninskii pr. 31, Moscow, 119991

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