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Crystal structure of EuCeCuS3


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Abstract

The crystal structure of EuCeCuS3, a complex sulfide synthesized for the first time, has been solved using X-ray powder diffraction data. Crystals are rhombic, space group Pnma, Ba2MnS3 structural type, a = 8.1023(1) Å, b = 4.0386(1) Å, c = 15.9022(2) Å, V = 520.36(1) Å3, Z = 4, ρcalcd = 5.767 g/cm3. The Eu,CeS7 polyhedron incorporates the Eu and Ce atoms, which are randomly disordered over two crystallographic sites. The bond lengths dEu,Ce–S range from 2.885 to 3.044 Å.

About the authors

A. V. Ruseikina

Tyumen State University

Author for correspondence.
Email: adeschina@mail.ru
Russian Federation, ul. Semakova 10, Tyumen, 625003

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