Email this article Study of isotope effect upon lithium iodide complexation with benzo-15-crown-5 in water–chloroform extraction system
- Authors: Shokurova N.A.1, Demina L.I.1,2, Zhilov V.I.1,2, Demin S.V.1,2, Tsivadze A.Y.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 61, No 6 (2016)
- Pages: 787-790
- Section: Physical Chemistry of Solutions
- URL: https://bakhtiniada.ru/0036-0236/article/view/166563
- DOI: https://doi.org/10.1134/S0036023616060176
- ID: 166563
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Abstract
Extraction characteristics of chloroform–water system in lithium iodide extraction with benzo-15-crown-5 (B15C5) were studied. The complexation of the crown ether with LiI in organic phase was shown by IR spectroscopy. Isotope effect multiplication was performed by extraction chromatography technique. The magnitude of isotope separation factor (α) for 6Li-7Li pair was 1.017. The light lithium isotope is concentrated in organic phase.
About the authors
N. A. Shokurova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
L. I. Demina
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; Leninskii pr. 31, Moscow, 119991
V. I. Zhilov
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: zhilov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; Leninskii pr. 31, Moscow, 119991
S. V. Demin
Frumkin Institute of Physical Chemistry and Electrochemistry; Kurnakov Institute of General and Inorganic Chemistry
Email: zhilov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991; Leninskii pr. 31, Moscow, 119991
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: zhilov@igic.ras.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
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