Email this article Transformations of CO2 in Two-Phase Systems C8F18–H2O and C6F6–H2O
- Authors: Vishnetskaya M.V.1, Ivanova M.S.1, Mel’nikov M.Y.2
-
Affiliations:
- Gubkin Russian State University of Gas and Oil
- Department of Chemistry
- Issue: Vol 73, No 5 (2018)
- Pages: 260-263
- Section: Article
- URL: https://bakhtiniada.ru/0027-1314/article/view/163771
- DOI: https://doi.org/10.3103/S0027131418050115
- ID: 163771
Cite item
Open Access
Access granted
Subscription Access
Abstract
The transformation of carbon dioxide in aqueous emulsions of perfluorons in the presence of oxygen in the air results in the formation of a mixture of oxalic acid and a minor set of organic compounds C4–C8. The maximum CO2 consumption occurs in the emulsion with the C8F18: H2O vol/vol ratio of 1: 0.42 at pH 2.4; the H2C2O4 yield is 11 mol %.
Keywords
About the authors
M. V. Vishnetskaya
Gubkin Russian State University of Gas and Oil
Author for correspondence.
Email: mvvishnetskaya@mail.ru
Russian Federation, Moscow, 119991
M. S. Ivanova
Gubkin Russian State University of Gas and Oil
Email: mvvishnetskaya@mail.ru
Russian Federation, Moscow, 119991
M. Ya. Mel’nikov
Department of Chemistry
Email: mvvishnetskaya@mail.ru
Russian Federation, Moscow, 119991
Supplementary files
