Separation of rare earth elements in the tributyl phosphate–Ln(NO3)3–Ca(NO3)2 system in the counter current process


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Abstract

The 40-step extraction process to separate rare earth elements (RЕEs) according to the praseodymium–cerium line with the use of mixer–settler extractors in a 100% TBP–Ln(NO3)3–Ca(NO3)2 system is implemented. A lanthanum–cerium concentrate containing less than 0.03 wt % of the remaining REEs is obtained. The flow diagram of the separation process of a rare earth (RE) concentrate isolated from phosphogypsum is considered.

About the authors

S. N. Igumnov

Department of Chemistry

Author for correspondence.
Email: igumnovs@gmail.com
Russian Federation, Moscow, 119991

A. V. Valkov

National Nuclear Research University

Email: igumnovs@gmail.com
Russian Federation, Moscow, 115409

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