电邮这篇文章 Spectral and photochemical properties of styrylquinoline–carbazole dyad in neutral and protonated forms
- 作者: Budyka M.F.1, Li V.M.1, Gavrishova T.N.1, Kitina P.V.2, Soulimenkov I.V.3
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隶属关系:
- Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry
- Faculty of Basic Physicochemical Engineering, Moscow State University
- Branch of Semenov Federal Research Center for Chemical Physics
- 期: 卷 59, 编号 2 (2025)
- 页面: 94-103
- 栏目: ФОТОХИМИЯ
- URL: https://bakhtiniada.ru/0023-1193/article/view/304490
- DOI: https://doi.org/10.31857/S0023119325020041
- EDN: https://elibrary.ru/algjns
- ID: 304490
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详细
Spectral-luminescent and photochemical properties of neutral and protonated forms of styrylquinoline – carbazole dyad SQ3Cbz, in which the carbazole fragment (Cbz) is linked to the 2-styrylquinoline (SQ) residue via an oxytrimethylene bridge, were studied. It was shown that in both forms of SQ3Cbz strong quenching of the Cbz fragment fluorescence is observed due to energy transfer to the SQ fragment via the Förster mechanism. In the protonated form of the dyad, where the proton is localized on the SQ fragment, a significant decrease in the quantum yields of trans-cis photoisomerization and fluorescence of the SQ fragment is observed, as well as a blue shift of its emission band compared to the model SQ chromophore. It is suggested that the observed effects are related to the formation of folded dyad conformers in which the SQ chromophore has a more rigid structure and/or the process of electron transfer from Cbz to the protonated SQ fragment. DFT calculations predict the possibility of the formation of folded dyad conformers that are stabilized by π-stacking interactions between Cbz and SQ fragments.
作者简介
M. Budyka
Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry
Email: budyka@icp.ac.ru
Chernogolovka, Russia
V. Li
Federal Research Center of Problems of Chemical Physics and Medicinal ChemistryChernogolovka, Russia
T. Gavrishova
Federal Research Center of Problems of Chemical Physics and Medicinal ChemistryChernogolovka, Russia
P. Kitina
Faculty of Basic Physicochemical Engineering, Moscow State UniversityMoscow, Russia
I. Soulimenkov
Branch of Semenov Federal Research Center for Chemical PhysicsChernogolovka, Russia
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