Synthesis of Ethyl-2-Dicyanomethylene-4-Methyl-6-Phenyl-3-Cyclohexene-1-Carboxylate and Molecular Agglomerates in Its Crystal Structure
- 作者: Ismiev A.I.1, Potekhin K.A.2, Maleev A.V.2, Maharramov A.M.1
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隶属关系:
- Baku State University
- Vladimir State University
- 期: 卷 60, 编号 12 (2019)
- 页面: 1896-1905
- 栏目: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/162237
- DOI: https://doi.org/10.1134/S0022476619120059
- ID: 162237
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详细
Three-component condensation of benzylideneacetone, ethyl acetoacetate, and malononitrile in the 1:1:1 molar ratio, respectively, in the presence of equimolar quantities of piperidine and glacial acetic acid is studied. The crystal structure of the reaction product (ethyl-2-dicyanomethylene-4-methyl-6-phenyl-3-cyclohexene-1-carboxylate) determined from XRD data by the method of atom-atom potentials contains energy traps in the form of double planar and double two-sided catchers. The energy traps lead to molecular agglomerates occurring in the crystal in the form of slightly deformed translationally identical hexagonal networks.
作者简介
A. Ismiev
Baku State University
Email: andr_mal@mail.ru
阿塞拜疆, Baku
K. Potekhin
Vladimir State University
Email: andr_mal@mail.ru
俄罗斯联邦, Vladimir
A. Maleev
Vladimir State University
编辑信件的主要联系方式.
Email: andr_mal@mail.ru
俄罗斯联邦, Vladimir
A. Maharramov
Baku State University
Email: andr_mal@mail.ru
阿塞拜疆, Baku
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