Molecular and Crystal Structure of (1S,2R)-1-{2-[(1S)-1-(Dimethylamino)Ethyl]Phenyl}-1,2-Diphenylethane-1,2-Diol

V. M. Demyanovich; I. N. Shishkina; K. A. Potekhin; A. V. Maleev; A. A. Gevorgyan

doi:10.1134/S0022476619040176

Molecular and Crystal Structure of (1S,2R)-1-{2-[(1S)-1-(Dimethylamino)Ethyl]Phenyl}-1,2-Diphenylethane-1,2-Diol

Авторлар: Demyanovich V.M.¹, Shishkina I.N.¹, Potekhin K.A.², Maleev A.V.², Gevorgyan A.A.²
Мекемелер:
1. Moscow State University
2. Vladimir State University
Шығарылым: Том 60, № 4 (2019)
Беттер: 654-661
Бөлім: Article
URL: https://bakhtiniada.ru/0022-4766/article/view/162102
DOI: https://doi.org/10.1134/S0022476619040176
ID: 162102

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Аннотация

The (R)-configuration of the carbinol center formed as a result of diastereospecific reduction of (2S)-2-{2-(1S)-1-(dimethylamino)ethyl]phenyl}-2-hydroxy-1,2-diphenylethanone is established by the XRD method. The analysis of shortened nonvalent intramolecular contacts testifies that the molecule is quite rigid, despite the presence of a large number of single valence bonds. Layered nature of molecular packaging is revealed.