Hexanuclear Na(I) complex with 3,5-dimethyl-1H-pyrazole and its anion

详细

The crystal structure of a hexanuclear Na(I) complex based on 3,5-dimethyl-1H-pyrazole (C₅H₈N₂) and its anion is determined (space group P2₁/c, a = 12.2194(5) Å, b = 24.1554(9) Å, c = 11.3311(4) Å, β = 109.942(1)°, V = 3143.99(8) ų, Z = 2). The crystal structure is formed by Na₆(C₅H₈N₂)₄(C₅H₇N₂)₆ molecules. Thermogravimetric studies show that the compound exhibits volatility at elevated temperatures. The compound can be used in chemical gas-phase deposition processes.