Email this article Structure of Two Complexes of N-Thiophosphorylated Thioamides with a Silver(I) Cation and Triphenylphosphine
- Authors: Litvinov I.A.1,2, Karamov F.A.2
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Affiliations:
- Arbuzov Institute of Organic and Physical Chemistry
- Tupolev National Research Technical University
- Issue: Vol 60, No 11 (2019)
- Pages: 1812-1817
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/162226
- DOI: https://doi.org/10.1134/S0022476619110155
- ID: 162226
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Abstract
In order to study the complexation properties of N-thiophosphorylated thioureas, thioamides, and thiosemicarbazides with the general formula RC(S)NHP(S)(OPri)2 (R = AlkNH, Alk2N, ArNH, PyNH, Ph, PhNHNH, NH2(Et)N) towards copper(I) and silver(I) cations, the molecular and crystal structures of silver(I) (triphenylphosphine-P)[N-(diisopropoxythiophosphoryl)thiobenzamide-S,S′] and silver(I) bis-(triphenylphosphine-P)[N-(diisopropoxythiophosphoryl)thiobenzamide-S,S′] are determined.
About the authors
I. A. Litvinov
Arbuzov Institute of Organic and Physical Chemistry; Tupolev National Research Technical University
Author for correspondence.
Email: litvinov@iopc.ru
Russian Federation, Kazan, Republic of Tatarstan; Kazan, Republic of Tatarstan
F. A. Karamov
Tupolev National Research Technical University
Email: litvinov@iopc.ru
Russian Federation, Kazan, Republic of Tatarstan
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