Crystallographic Analysis of Compounds with Lindqvist Polyanions: Coherent Assembly, Symmetry, Stability
- Authors: Borisov S.V.1, Magarill S.A.1, Pervukhina N.V.1
-
Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Issue: Vol 59, No 3 (2018)
- Pages: 612-617
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161916
- DOI: https://doi.org/10.1134/S0022476618030150
- ID: 161916
Cite item
Abstract
The crystallographic analysis of the structure of three inorganic compounds with Lindqvist polyanions establishes that their structural arrangement is determined by the geometry and symmetry of the [M6] cation octahedron by the coherent assembly of [M6O19] building blocks. The relative stability of the structures is estimated from the number of degrees of freedom of their atoms and the fundamental volumes characterizing the degree of symmetrization of the structures.
About the authors
S. V. Borisov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk
S. A. Magarill
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk
Supplementary files
