A Homochiral Coordination Polymer Based on Copper(II), S-Malic Acid, and Biphenyl-3,3′,5,5′-Tetracarboxilic Acid


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Abstract

The [Cu8(S-mal)4(bptc)(H2O)12] · 0.5H4bptc · 7.5H2O coordination polymer is obtained by heating the copper(II) nitrate, S-malic acid (H3mal), and biphenyl-3,3′,5,5′-tetracarboxylic (H4bptc) acid solution in the water-N,N-diethylformamide mixture. The crystal structure is determined from XRD data. The compound has a three-dimensional homochiral framework with channels filled by crystallization molecules of tetracarboxylic acid and water. The composition and structure of the coordination polymer obtained are confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetric analysis, and elemental analysis.

About the authors

M. S. Zavakhina

Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University

Author for correspondence.
Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk

D. G. Samsonenko

Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University

Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk

V. P. Fedin

Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University

Email: cluster@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk

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