Email this article Crystal Structures of New Chalcogenide- Containing Yttrium Orthosilicates Y2SiO4Q (Q = S, Se)
- Authors: Kiryakov A.S.1,2, Piryazev D.A.1, Tarasenko M.S.1, Naumov N.G.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 59, No 3 (2018)
- Pages: 635-640
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161919
- DOI: https://doi.org/10.1134/S0022476618030186
- ID: 161919
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Abstract
Compounds Y2SiO4Q (Q = S, Se) are obtained by the interaction of oxides and elemental substances in cesium chloride flux. The structures of these compounds are determined by the single crystal XRD analysis. These compounds isostructural and crystallize in the space group Pbcm with the following parameters: Y2SiO4S (I) a = 6.0462(8) Å, b = 6.8976(9) Å, c = 10.6558(13) Å, V = 444.39(10) Å3; Y2SiO4Se (II) a = 5.9935(7) Å, b = 6.9216(8) Å, c = 10.7688(12) Å, V = 446.74(9) Å3. The measured fluxing points are 1650±15 °С for I and 1850±15 °С for II.
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About the authors
A. S. Kiryakov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: tarasen@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
D. A. Piryazev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: tarasen@niic.nsc.ru
Russian Federation, Novosibirsk
M. S. Tarasenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: tarasen@niic.nsc.ru
Russian Federation, Novosibirsk
N. G. Naumov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: tarasen@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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