Structure of A Ni(Ii) Mixed Ligand Complex with 3-Imidazoline Nitroxide, ISO-Propanol, and Water
- Authors: Romanenko G.V.1, Fursova E.Y.1, Letyagin G.A.1,2, Ovcharenko V.I.1
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Affiliations:
- International Tomography Center, Siberian Branch
- Novosibirsk State University
- Issue: Vol 59, No 2 (2018)
- Pages: 384-387
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161883
- DOI: https://doi.org/10.1134/S002247661802018X
- ID: 161883
Cite item
Abstract
A mixed ligand complex of Ni(II) with 3-imidazoline nitroxide and iso-propanol [NiL2(i-C3H7OH)2] is sensitive to atmospheric moisture. It is determined that at a high humidity, the air contacts with the mother solution of the compound in iso-propanol with the precipitated [NiL2(i-C3H7OH)2] crystals leads to their spontaneous transformation into [NiL2(H2O)]·i-C3H7OH crystals whose structure is described in the present paper.
Keywords
About the authors
G. V. Romanenko
International Tomography Center, Siberian Branch
Author for correspondence.
Email: romanenko@tomo.nsc.ru
Russian Federation, Novosibirsk
E. Yu. Fursova
International Tomography Center, Siberian Branch
Email: romanenko@tomo.nsc.ru
Russian Federation, Novosibirsk
G. A. Letyagin
International Tomography Center, Siberian Branch; Novosibirsk State University
Email: romanenko@tomo.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
V. I. Ovcharenko
International Tomography Center, Siberian Branch
Email: romanenko@tomo.nsc.ru
Russian Federation, Novosibirsk
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