Structure and Photocatalytic Properties of a 3D Zinc(II) Triazolate Coordination Polymer Combining Hydroxyl and Formate Anions as the Auxiliary Coligands

X.-D. Fang; L.-B. Yang; A.-N. Dou; A.-X. Zhu; Q.-Q. Xu

doi:10.1134/S002247661806029X

Structure and Photocatalytic Properties of a 3D Zinc(II) Triazolate Coordination Polymer Combining Hydroxyl and Formate Anions as the Auxiliary Coligands

Authors: Fang X.¹, Yang L.¹, Dou A.¹, Zhu A.¹, Xu Q.¹
Affiliations:
1. Faculty of Chemistry and Chemical Engineering
Issue: Vol 59, No 6 (2018)
Pages: 1450-1455
Section: Article
URL: https://bakhtiniada.ru/0022-4766/article/view/161749
DOI: https://doi.org/10.1134/S002247661806029X
ID: 161749

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Abstract

A new 3D zinc coordination polymer, namely {[Zn₄(dmtz)₃(OH)₃(HCOO)](NO₃)}_n (1, Hdmtz = 3,5- dimethyl-1,2,4-triazole), is hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, and single crystal X-ray diffraction analysis. The complex features a (3,4,5)- connected 3D cation framework constructed by μ₃-bridging dmtz with hydroxyl and formate anions as the auxiliary ligands. Moreover, the photocatalytic properties of 1 are also investigated.