Crystallographic Analysis of the Structure of LaBiI6·13H2O and NdBiI6·13H2O. Sublattice of Iodine Atoms: A Common Skeleton of the Structures
- Authors: Borisov S.V.1, Pervukhina N.V.1,2, Magarill S.A.1
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Issue: Vol 59, No 6 (2018)
- Pages: 1387-1391
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161739
- DOI: https://doi.org/10.1134/S0022476618060197
- ID: 161739
Cite item
Abstract
The crystallographic analysis of the recently determined structures of LaBiI6·13H2O and NdBiI6·13H2O reveals that their common basis is a sublattice of iodine anions built of coherently assembled octahedral I6 fragments. The relationship between the parameters of orthorhombic and monoclinic unit cells of these structures is shown and their symmetry features are discussed.
About the authors
S. V. Borisov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk
N. V. Pervukhina
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
S. A. Magarill
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: borisov@niic.nsc.ru
Russian Federation, Novosibirsk
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