Study of the complexes of iron(II) dicyanamide and isothiocyanate with 2-(2-tert-butyltetrazol-5-yl)pyridine
- Авторы: Shakirova O.G.1, Lavrenova L.G.2,3, Kuratieva N.V.2,3, Bogomyakov A.S.3,4, Sheludyakova L.A.2,3, Mosalkova A.P.5, Grigoriev Y.V.5
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Учреждения:
- Komsomolsk-on-Amur State Technical University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- International Tomography Center, Siberian Branch
- Research Institute for Physical Chemical Problems of the Belarusian State University
- Выпуск: Том 58, № 5 (2017)
- Страницы: 919-925
- Раздел: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161490
- DOI: https://doi.org/10.1134/S0022476617050092
- ID: 161490
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Аннотация
Iron(II) dicyanamide and isothiocyanate compounds with 2-(2-tert-butyltetrazol-5-yl)pyridine (L) of the composition [FeL2(C2N3)2]•2H2O (I) and [FeL2(NCS)2]H2O (II) are synthesized and studied. The compounds are examined using powder and single crystal XRD (for I), electron (diffuse reflectance spectra) and IR spectroscopy, static magnetic susceptibility. The analysis of the dependence μeff(Т) indicates that the exchange interactions of antiferromagnetic nature appear between the iron(II) ions at temperatures below 50 K.
Об авторах
O. Shakirova
Komsomolsk-on-Amur State Technical University
Email: ludm@niic.nsc.ru
Россия, Komsomolsk-on-Amur
L. Lavrenova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Автор, ответственный за переписку.
Email: ludm@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
N. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: ludm@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
A. Bogomyakov
Novosibirsk National Research State University; International Tomography Center, Siberian Branch
Email: ludm@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
L. Sheludyakova
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: ludm@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
A. Mosalkova
Research Institute for Physical Chemical Problems of the Belarusian State University
Email: ludm@niic.nsc.ru
Белоруссия, Minsk
Yu. Grigoriev
Research Institute for Physical Chemical Problems of the Belarusian State University
Email: ludm@niic.nsc.ru
Белоруссия, Minsk
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