In situ X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH3)4][OsCl6]
- Авторы: Asanova T.I.1, Asanov I.P.1,2, Kim M.3, Korenev S.V.1,2
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Учреждения:
- Nikolaev Institute of Inorganic Chemistry Siberian Branch
- Novosibirsk National Research University
- Beamline Research Division
- Выпуск: Том 58, № 5 (2017)
- Страницы: 901-910
- Раздел: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161485
- DOI: https://doi.org/10.1134/S0022476617050079
- ID: 161485
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Аннотация
In the paper results of the investigation of the thermal decomposition process of double complex salt [Pt(NH3)4][OsCl6] by x-ray absorption (XAFS) and photoelectron (XPS) spectroscopies have been presented. The data obtained allows a mechanism of the thermal decomposition to be refined. An influence of size effect and nanoalloy formation on chemical shift of Pt and Os is discussed.
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Об авторах
T. Asanova
Nikolaev Institute of Inorganic Chemistry Siberian Branch
Автор, ответственный за переписку.
Email: nti@niic.nsc.ru
Россия, Novosibirsk
I. Asanov
Nikolaev Institute of Inorganic Chemistry Siberian Branch; Novosibirsk National Research University
Email: nti@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
M.-G. Kim
Beamline Research Division
Email: nti@niic.nsc.ru
Республика Корея, Pohang
S. Korenev
Nikolaev Institute of Inorganic Chemistry Siberian Branch; Novosibirsk National Research University
Email: nti@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
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