Crystal and molecular structure of the derivatives of perchlorate (4Н-chromen-4-yl) and (9Н-xanthene-9-yl) triphenyl phosphonium


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The X-ray diffraction study of new derivatives of perchlorate (9Н-xanthene-9-yl) and (4H-chromen-4-yl) triphenyl phosphonium is performed. It is demonstrated that the change in the molecular structure leading to a change in the degree of benzoannelation does not affect the phosphorus–carbon bond length. It is determined that perchlorate (2-phenyl-4Н-chromen-4-yl) triphenyl phosphonium сrystallizes as two polymorphs.

作者简介

A. Utenyshev

Institute of Problems of Chemical Physics

编辑信件的主要联系方式.
Email: uten@icp.ac.ru
俄罗斯联邦, Chernogolovka, Moscow Region

V. Tkachev

Institute of Problems of Chemical Physics; Institute of Physiological Active Compounds

Email: uten@icp.ac.ru
俄罗斯联邦, Chernogolovka, Moscow Region; Chernogolovka, Moscow Region

N. Tkacheva

Institute of Problems of Chemical Physics

Email: uten@icp.ac.ru
俄罗斯联邦, Chernogolovka, Moscow Region

A. Bumber

Institute of Problems of Chemical Physics

Email: uten@icp.ac.ru
俄罗斯联邦, Chernogolovka, Moscow Region

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