Crystal structures of [M(Еn)3](ReO4)2 (M = Ni, Zn)


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The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.

作者简介

S. Khranenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch

Email: grom@niic.nsc.ru
俄罗斯联邦, Novosibirsk

E. Bykova

Bayerisches Geoinstitut

Email: grom@niic.nsc.ru
德国, Bayreuth

A. Zadesenets

Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University

Email: grom@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk

S. Gromilov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University

编辑信件的主要联系方式.
Email: grom@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk

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