Email this article Crystal structures of [M(Еn)3](ReO4)2 (M = Ni, Zn)
- Authors: Khranenko S.P.1, Bykova E.A.2, Zadesenets A.V.1,3, Gromilov S.A.1,3
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Bayerisches Geoinstitut
- Novosibirsk National Research State University
- Issue: Vol 58, No 1 (2017)
- Pages: 90-96
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/161044
- DOI: https://doi.org/10.1134/S0022476617010139
- ID: 161044
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Abstract
The structures of two isostructural phases of [M(Еn)3](ReO4)2 (M = Ni, Zn; Еn is ethylenediamine) are studied. The crystal structures belong to the triclinic system, but demonstrate a pseudohexagonal packing motif. It is shown that the product of thermal decomposition of [Zn(Еn)3](ReO4)2 (hydrogen atmosphere, 400 °C) is a homogeneous mixture of nanocrystalline zinc and rhenium powders with coherent scattering regions of ~30 nm.
About the authors
S. P. Khranenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk
E. A. Bykova
Bayerisches Geoinstitut
Email: grom@niic.nsc.ru
Germany, Bayreuth
A. V. Zadesenets
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
S. A. Gromilov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Author for correspondence.
Email: grom@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
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