Отправить статью по E-mail X-ray diffraction study of α-34S within temperature range 100–363 K
- Авторы: Gromilov S.A.1,2, Piryazev D.A.1,2, Egorov N.B.3, Akimov D.V.3
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Учреждения:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk National Research State University
- National Research Tomsk Polytechnic University
- Выпуск: Том 57, № 8 (2016)
- Страницы: 1663-1666
- Раздел: Brief Communications
- URL: https://bakhtiniada.ru/0022-4766/article/view/160492
- DOI: https://doi.org/10.1134/S0022476616080230
- ID: 160492
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Аннотация
α-34S has been studied with X-ray crystallography within 100–363 K. Anisotropy of the evolution of the parameters of the orthorhombic unit cell has been examined. The absolute increase in the cell volume is 154 Å3, and the relative one is 4.8%. It has been demonstrated that in the studied range the intramolecular S–S bond lengths are shortened at average by 0.006 Å on heating. At the same time, intermolecular contacts S…S shorter than the sum of van der Waals radii demonstrate average elongation of 0.097 Å.
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Об авторах
S. Gromilov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Автор, ответственный за переписку.
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
D. Piryazev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk National Research State University
Email: grom@niic.nsc.ru
Россия, Novosibirsk; Novosibirsk
N. Egorov
National Research Tomsk Polytechnic University
Email: grom@niic.nsc.ru
Россия, Tomsk
D. Akimov
National Research Tomsk Polytechnic University
Email: grom@niic.nsc.ru
Россия, Tomsk
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