Structural characterization, photophysical and BSA binding interaction studies of 4,4′-bis(benzimidazolyl)-2,2′-bipyridine


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Abstract

The title compound is synthesized from the precursors 1,2-diaminobenzene and 2,2′-bipyridine-4,4′-dicarboxylic acid (dcbpy) and characterized using ESI-Mass, 1H NMR, FT-IR and single crystal X-ray analysis. We are the first to report the crystal structure of the 4,4′-bis(benzimidazolyl)-2,2′-bipyridine (bimbpy) ligand. The photophysical properties of the compound in dimethyl sulfoxide and in the aqueous medium are studied. The interaction studies of bimbpy with bovine serum albumin (BSA) were performed with the fluorescence technique and it strongly binds with BSA.

About the authors

K. Swarnalatha

Department of Chemistry

Author for correspondence.
Email: swarnalatha@msuniv.ac.in
India, Tirunelveli, Tamil Nadu

P. Rathnamala

Department of Chemistry

Email: swarnalatha@msuniv.ac.in
India, Tirunelveli, Tamil Nadu

A. A. Babu

Department of Chemistry

Email: swarnalatha@msuniv.ac.in
India, Tirunelveli, Tamil Nadu

N. Bhuvanesh

Department of Chemistry and Biochemistry

Email: swarnalatha@msuniv.ac.in
United States, Austin

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