Structural characterization, photophysical and BSA binding interaction studies of 4,4′-bis(benzimidazolyl)-2,2′-bipyridine
- Authors: Swarnalatha K.1, Rathnamala P.1, Babu A.A.1, Bhuvanesh N.2
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Affiliations:
- Department of Chemistry
- Department of Chemistry and Biochemistry
- Issue: Vol 57, No 8 (2016)
- Pages: 1554-1560
- Section: Article
- URL: https://bakhtiniada.ru/0022-4766/article/view/160377
- DOI: https://doi.org/10.1134/S0022476616080096
- ID: 160377
Cite item
Abstract
The title compound is synthesized from the precursors 1,2-diaminobenzene and 2,2′-bipyridine-4,4′-dicarboxylic acid (dcbpy) and characterized using ESI-Mass, 1H NMR, FT-IR and single crystal X-ray analysis. We are the first to report the crystal structure of the 4,4′-bis(benzimidazolyl)-2,2′-bipyridine (bimbpy) ligand. The photophysical properties of the compound in dimethyl sulfoxide and in the aqueous medium are studied. The interaction studies of bimbpy with bovine serum albumin (BSA) were performed with the fluorescence technique and it strongly binds with BSA.
About the authors
K. Swarnalatha
Department of Chemistry
Author for correspondence.
Email: swarnalatha@msuniv.ac.in
India, Tirunelveli, Tamil Nadu
P. Rathnamala
Department of Chemistry
Email: swarnalatha@msuniv.ac.in
India, Tirunelveli, Tamil Nadu
A. A. Babu
Department of Chemistry
Email: swarnalatha@msuniv.ac.in
India, Tirunelveli, Tamil Nadu
N. Bhuvanesh
Department of Chemistry and Biochemistry
Email: swarnalatha@msuniv.ac.in
United States, Austin
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