Synthesis and Properties of a Carbon Monoxide Oxidation Catalyst Based on Platinum and Plasma-Chemical Titanium Nitride
- Авторлар: Vershinin N.N.1, Berestenko V.I.1, Efimov O.N.1, Kurkin E.N.1,2, Kabachkov E.N.1,2
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Мекемелер:
- Institute of Problems of Chemical Physics, Russian Academy of Sciences
- Scientific Center in Chernogolovka, Russian Academy of Sciences
- Шығарылым: Том 53, № 5 (2019)
- Беттер: 400-406
- Бөлім: Plasma Chemistry
- URL: https://bakhtiniada.ru/0018-1439/article/view/157752
- DOI: https://doi.org/10.1134/S001814391905014X
- ID: 157752
Дәйексөз келтіру
Аннотация
A CO oxidation catalyst that includes Pt clusters applied on nanosized TiN supports with a particle size of 18 and 36 nm has been synthesized. The catalyst has been studied using TEM, X-ray powder diffraction, and XPS methods. It has been found that platinum clusters formed on the support surface are covered with a mixture of platinum and platinum oxide. The coherent scattering range of the Pt cluster is close to 8 nm on a support with titanium nitride particles of 18 nm. The catalytic properties in the reaction of CO oxidation at 295 K and low CO concentrations (<100 mg/m3) have been examined. It has been found that when the platinum content in the catalyst is 9 to 15 wt %, the CO oxidation rate is 120 times higher than that on platinum black with a specific surface area of 30 m2/g. The catalysts are promising for use in catalytic systems for air purification.
Негізгі сөздер
Авторлар туралы
N. Vershinin
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Хат алмасуға жауапты Автор.
Email: vernik@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
V. Berestenko
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: vernik@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
O. Efimov
Institute of Problems of Chemical Physics, Russian Academy of Sciences
Email: vernik@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432
E. Kurkin
Institute of Problems of Chemical Physics, Russian Academy of Sciences; Scientific Center in Chernogolovka, Russian Academy of Sciences
Email: vernik@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432; Chernogolovka, Moscow oblast, 142432
E. Kabachkov
Institute of Problems of Chemical Physics, Russian Academy of Sciences; Scientific Center in Chernogolovka, Russian Academy of Sciences
Email: vernik@icp.ac.ru
Ресей, Chernogolovka, Moscow oblast, 142432; Chernogolovka, Moscow oblast, 142432
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