Photochemical processes in graphene oxide films


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Аннотация

Experimentally revealed features of thermal and photochemical deoxidation of graphene oxide (GO) in films are reported. A difference in mechanism between the photoreduction and thermal reduction of GO has been shown. The mechanism of photochemical deoxidation of graphene oxide has been rationalized using the concepts of molecular photochemistry. A new model of photoelimination of molecular oxygen from epoxy groups on graphene nanosheet has been proposed. The photoprocesses lead to growing of π-domains of graphene.

Авторлар туралы

V. Smirnov

Institute of Problems of Chemical Physics; Tomsk State University

Хат алмасуға жауапты Автор.
Email: vas@icp.ac.ru
Ресей, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; pr. Lenina 36, Tomsk, 634050

N. Denisov

Institute of Problems of Chemical Physics

Email: vas@icp.ac.ru
Ресей, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

V. Plotnikov

Tomsk State University; Photochemistry Center

Email: vas@icp.ac.ru
Ресей, pr. Lenina 36, Tomsk, 634050; ul. Novatorov 7a, Moscow, 119421

M. Alfimov

Tomsk State University; Photochemistry Center

Email: vas@icp.ac.ru
Ресей, pr. Lenina 36, Tomsk, 634050; ul. Novatorov 7a, Moscow, 119421

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